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188宝金博页面版: 电缆保护管用HDPE_AMWs复合材料的制备与性能研究_张振宇
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内容提示: 101 加工与应用NO.08 2026 塑料科技 Plastics Science and Technology电缆保护管用HDPE/AMWs复合材料的制备与性能研究张振宇1 ,韩绪鹏 1 ,贝慧婷 2 *(1.广西电力职业技术学院,广西 南宁 530299;2.广西建设职业技术学院土木工程学院,广西 南宁 530007)摘 要: 为改善高密度聚乙烯(HDPE)电缆保护管的性能并推动人造岗石废渣(AMWs)的高值化利用,采用熔融共混与注塑成型制备HDPE基复合材料,系统表征其微观结构、结晶行为、力学性能、热变形及电气绝缘性能。结果表明:AMWs表面的有机层可作为异相成核位点,显著调控HDPE结晶。当填料添加量为50 phr时,HDPE/AMWs复合材料的结...
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101 加工与应用NO.08 2026 塑料科技 Plastics Science and Technology电缆保护管用HDPE/AMWs复合材料的制备与性能研究张振宇1 ,韩绪鹏 1 ,贝慧婷 2 *(1.广西电力职业技术学院,广西 南宁 530299;2.广西建设职业技术学院土木工程学院,广西 南宁 530007)摘 要: 为改善高密度聚乙烯(HDPE)电缆保护管的性能并推动人造岗石废渣(AMWs)的高值化利用,采用熔融共混与注塑成型制备HDPE基复合材料,系统表征其微观结构、结晶行为、力学性能、热变形及电气绝缘性能。结果表明:AMWs表面的有机层可作为异相成核位点,显著调控HDPE结晶。当填料添加量为50 phr时,HDPE/AMWs复合材料的结晶度高达88.5%,拉伸强度为23.3 MPa,高于同添加量下的CaCO 3 体系。在热性能方面,中低添加量时AMWs 体系热变形性能更优。当填料添加量为 70 phr 时,CaCO 3 体系热变形温度升至 91.3 ℃,弯曲模量达2 341 MPa,表现出更优的耐高温变形能力与刚性。在电性能方面,当填料添加量为70 phr时,两类材料的体积电阻率均高于1.60×10 13 Ω·m,击穿场强稳定在22 kV/mm,满足电缆保护管绝缘要求。AMWs可通过诱导结晶提升材料拉伸强度与中低添加量下的热稳定性,并保持良好绝缘性,具有替代CaCO 3 制备高性能电缆保护管材料的潜力。关键词:岗石废渣;碳酸钙;高密度聚乙烯;电缆保护管;电气性能中图分类号: TQ325.1; TB332 文献标志码:A 文章编号:1005-3360(2026)08-0101-06 DOI:10.15925/j.cnki.issn1005-3360.2026.08.018Preparation and Properties Study of HDPE/AMWs Composites for Cable Protection PipesZHANG Zhenyu 1 , HAN Xupeng 1 , BEI Huiting 2 *(1. Guangxi Electrical Polytechnic Institute, Nanning 530299, China; 2. School of Civil Engineering Guangxi Polytechnic of Construction, Nanning 530007, China)Abstract: To improve the performance of high-density polyethylene (HDPE) cable protection pipes and promote the high-value utilization of artificial marble waste residues (AMWs), HDPE-based composites were prepared via melt blending and injection molding. The microstructure, crystallization behavior, mechanical properties, thermal deformation, and electrical insulation performance were systematically characterized. The results showed that the organic layer on the surface of AMWs could serve as heterogeneous nucleation sites, significantly regulating the crystallization of HDPE. At a filler loading of 50 phr, the HDPE/AMWs composites achieved a crystallinity as high as 88.5%, with a tensile strength of 23.3 MPa, which was higher than that of the CaCO 3 system at the same loading. In terms of thermal properties, the AMWs system exhibited better thermal deformation performance at low and medium filler loadings. At a filler loading of 70 phr, the CaCO 3 system showed a heat deflection temperature of 91.3 ℃ and a flexural modulus of 2 341 MPa, indicating superior resistance to high-temperature deformation and higher rigidity. Regarding electrical properties, both composite systems at a filler loading of 70 phr exhibited volume resistivities above 1.60×10 13 Ω·m and stable breakdown strengths of around 22 kV/mm, meeting the insulation requirements for cable protection pipes. In conclusion, AMWs can enhance the tensile strength and thermal stability at low and medium filler loadings through induced crystallization, while maintaining good insulation performance. This demonstrates their potential to replace CaCO 3 in the preparation of high-performance cable protection pipe materials.Keywords: AMWs; CaCO 3 ; HDPE; Cable protection pipe; Electrical properties收稿日期Submitted date 2025-12-28;修回日期Revised date 2026-01-16;录用日期Accepted date 2026-02-06基金项目:2023 年度广西高校中青年教师科研基础能力提升项目(2023KY1348);2024 年度广西职业188宝金博页面版教学改革研究项目(GXGZJG2024B066)*联系人,bay624@qq.com引用本文:张振宇,韩绪鹏,贝慧婷.电缆保护管用HDPE/AMWs复合材料的制备与性能研究[J].塑料科技,2026,54(8):101-106.Citation:ZHANG Z Y, HAN X P, BEI H T. Preparation and properties study of HDPE/AMWs composites for cable protection pipes[J]. Plastics Science and Technology, 2026, 54(8): 101-106.网络首发时间:2026-08-31 17:14:06 网络首发地址:https://link.cnki.net/urlid/21.1145.TQ.20260830.2209.011
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